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A Dodecanuclear Copper(II) Cage Self-Assembled from Six Dicopper Building Units

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dc.contributor.author Ghosh, Aoke Kumar
dc.contributor.author Pait, Moumita
dc.contributor.author Clérac, Rodolphe
dc.contributor.author Mathoniere, Corine
dc.contributor.author Bertolasi, Valerio
dc.contributor.author Frontera Beccaria, Antonio
dc.contributor.author Bauzá Riera, Antonio
dc.contributor.author Pramanik, Kausikisankar
dc.contributor.author Ray, Debashis
dc.date.accessioned 2018-09-24T11:00:05Z
dc.identifier.uri http://hdl.handle.net/11201/147617
dc.description.abstract [eng] Reaction of the dinucleating phenol-based ligand, H3bpmp (2,6-bis-[(3-hydroxy-propylimino)-methyl]- 4-methyl-phenol), with Cu2+ ions in the presence of a hybrid base (NEt3 and NaN3) necessary for the in situ generation of required numbers of hydroxido ions, results in the formation of a novel NO3 − capped and HO− supported {Cu12} coordination complex {Cu6(μ3-OH)3(μ3-Hbpmp)3(μ3-NO3)}2(NO3)2(OH)2· 2H2O·2MeOH (1). When the components are combined in right proportions (metal : ligand : NEt3 : NaN3 = 2 : 1 : 3 : 2) in MeOH, twelve Cu2+ ions assemble in a cuboctahedral geometry, containing six square and eight triangular faces around a considerable void space. Six of the eight [Cu3] triangular faces are bound by the six Hbpmp2− ligands with six free pendant propanol arms around the central hexagonal plane. X-ray structure determination indicates new geometrical features for the core formation and reveals the face-capping potential of the H3bpmp ligand for the growth of a cuboctahedral coordination cage with the support of anions like HO− and NO3 −. The experimentally observed (J/kB = −173 K) strong antiferromagnetic coupling within the Cu12 complex has been justified by the DFT calculations.
dc.format application/pdf
dc.relation.isformatof Versió postprint del document publicat a: https://doi.org/10.1039/C3DT53144A
dc.relation.ispartof Dalton Transactions, 2014, vol. 43, p. 4076-4085
dc.rights (c) Ghosh, Aoke Kumar et al., 2014
dc.subject.classification 54 - Química
dc.subject.other 54 - Chemistry. Crystallography. Mineralogy
dc.title A Dodecanuclear Copper(II) Cage Self-Assembled from Six Dicopper Building Units
dc.type info:eu-repo/semantics/article
dc.type info:eu-repo/semantics/acceptedVersion
dc.date.updated 2018-09-24T11:00:05Z
dc.date.embargoEndDate info:eu-repo/date/embargoEnd/2075-01-01
dc.embargo 2075-01-01
dc.rights.accessRights info:eu-repo/semantics/embargoedAccess
dc.identifier.doi https://doi.org/10.1039/C3DT53144A


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