Surprising behaviour of M¿CO(lone pair)···pi(arene) interactions in the solid state of fluorinated oxaphosphirane complexes

dc.contributor.author	Murcia-García, Cristina
dc.contributor.author	Bauzá Riera, Antonio
dc.contributor.author	Frontera Beccaria, Antonio
dc.contributor.author	Streubel, Rainer
dc.date.accessioned	2018-09-24T11:07:36Z
dc.identifier.uri	http://hdl.handle.net/11201/147619
dc.description.abstract	[eng] We report the synthesis and X-ray characterization of several oxaphosphirane tungstenĲ0) complexes especially designed to analyse the intramolecular W-CO(lone pair)⋯πĲarene) interaction. The unexpected behaviour of this interaction in the solid state of oxaphosphirane complexes with different degrees of fluorination is rationalized by means of DFT calculations using orbital analysis and Bader's theory of "atoms-in-molecules".
dc.format	application/pdf
dc.relation.isformatof	Versió postprint del document publicat a: https://doi.org/10.1039/C5CE00104H
dc.relation.ispartof	Crystengcomm, 2015, vol. 17, p. 1769-1772
dc.rights	(c) Murcia-García, Cristina et al., 2015
dc.subject.classification	54 - Química
dc.subject.other	54 - Chemistry. Crystallography. Mineralogy
dc.title	Surprising behaviour of M¿CO(lone pair)···pi(arene) interactions in the solid state of fluorinated oxaphosphirane complexes
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/acceptedVersion
dc.date.updated	2018-09-24T11:07:37Z
dc.date.embargoEndDate	info:eu-repo/date/embargoEnd/2075-01-01
dc.embargo	2075-01-01
dc.rights.accessRights	info:eu-repo/semantics/embargoedAccess
dc.identifier.doi	https://doi.org/10.1039/C5CE00104H