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Surprising behaviour of M¿CO(lone pair)···pi(arene) interactions in the solid state of fluorinated oxaphosphirane complexes

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dc.contributor.author Murcia-García, Cristina
dc.contributor.author Bauzá Riera, Antonio
dc.contributor.author Frontera Beccaria, Antonio
dc.contributor.author Streubel, Rainer
dc.date.accessioned 2018-09-24T11:07:36Z
dc.identifier.uri http://hdl.handle.net/11201/147619
dc.description.abstract [eng] We report the synthesis and X-ray characterization of several oxaphosphirane tungstenIJ0) complexes especially designed to analyse the intramolecular W-CO(lone pair)⋯πIJarene) interaction. The unexpected behaviour of this interaction in the solid state of oxaphosphirane complexes with different degrees of fluorination is rationalized by means of DFT calculations using orbital analysis and Bader's theory of "atoms-in-molecules".
dc.format application/pdf
dc.relation.isformatof Versió postprint del document publicat a: https://doi.org/10.1039/C5CE00104H
dc.relation.ispartof Crystengcomm, 2015, vol. 17, p. 1769-1772
dc.rights (c) Murcia-García, Cristina et al., 2015
dc.subject.classification 54 - Química
dc.subject.other 54 - Chemistry. Crystallography. Mineralogy
dc.title Surprising behaviour of M¿CO(lone pair)···pi(arene) interactions in the solid state of fluorinated oxaphosphirane complexes
dc.type info:eu-repo/semantics/article
dc.type info:eu-repo/semantics/acceptedVersion
dc.date.updated 2018-09-24T11:07:37Z
dc.date.embargoEndDate info:eu-repo/date/embargoEnd/2075-01-01
dc.embargo 2075-01-01
dc.rights.accessRights info:eu-repo/semantics/embargoedAccess
dc.identifier.doi https://doi.org/10.1039/C5CE00104H


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