The turbulent structure parameters of temperature (C T 2 ) and humidity (C Q their cross-structure parameter (C QT ), are investigated using data collected with the airborne- measurement platform Helipod during the LITFASS-2003 campaign. The flights took place within the atmospheric surface layer over heterogeneous terrain including forests, a lake and farmland. We find variability in C T 2 along such flight legs, with values of C T 2 over forested surfaces one order of magnitude larger than over farmland, and two orders of magnitude larger 2 and than over the lake. However, a quantitative relationship between the magnitude of C Q the surface type is not found, most likely due to a similar surface latent heat flux between the land-use types. However, when the different flight legs are taken together and data grouped by 2 are significantly lower over the lake than over the other surfaces. land-use type, values of C Q A classification of C QT is only possible between water and land surfaces, with lower values over water. We find the correlation coefficient R QT in the range of 0.4-1.0, which is less than unity, and thus violates the assumption of unity in Monin-Obukhov similarity theory.