Application of a novel 2D cadmium(II)-MOF in the formation of a photo-switch with substantial onoff ratio

Roy, Sumit; Dey, Arka; Ray, Partha Patrim; Ortega-Castro, Joaquin; Frontera Beccaria, Antonio; Chattopadhyay, Shouvick

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dc.contributor.author	Roy, Sumit
dc.contributor.author	Dey, Arka
dc.contributor.author	Ray, Partha Patrim
dc.contributor.author	Ortega-Castro, Joaquin
dc.contributor.author	Frontera Beccaria, Antonio
dc.contributor.author	Chattopadhyay, Shouvick
dc.date.accessioned	2018-09-19T11:35:11Z
dc.identifier.uri	http://hdl.handle.net/11201/147501
dc.description.abstract	[eng] A novel thiocyanate bridged 2D MOF, [CdL(l-1,3-SCN)2]n, [HL = 2-(2-(ethylamino)ethyliminomethyl)-6-ethoxyphenol] has been synthesized and characterized by X-ray crystallography. The band gap of the synthesized material in the solid state has been determined by experimental measurements and compared with the theoretical value obtained from DFT calculations. For the first time, the single crystal X-ray crystallography of a MOF has been reported along with its applicability in photosensitive devices.
dc.format	application/pdf
dc.relation.isformatof	Versió postprint del document publicat a: https://doi.org/10.1039/C5CC04323A
dc.relation.ispartof	Chemical Communications, 2015, p. 12974-12976
dc.rights	(c) Roy, Sumit et al., 2015
dc.subject.classification	54 - Química
dc.subject.other	54 - Chemistry. Crystallography. Mineralogy
dc.title	Application of a novel 2D cadmium(II)-MOF in the formation of a photo-switch with substantial onoff ratio
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/acceptedVersion
dc.date.updated	2018-09-19T11:35:12Z
dc.date.embargoEndDate	info:eu-repo/date/embargoEnd/2075-01-01
dc.embargo	2075-01-01
dc.subject.keywords	Cadmium complex
dc.subject.keywords	MOF
dc.subject.keywords	DFT calculations
dc.rights.accessRights	info:eu-repo/semantics/embargoedAccess
dc.identifier.doi	https://doi.org/10.1039/C5CC04323A