Non-covalent sp3 carbon bonding with ArCF3 is analogous to CH-pi interactions.
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Non-covalent sp3 carbon bonding with ArCF3 is analogous to CH-pi interactions.
Bauzá Riera, Antonio
;
Mooibroek, Tiddo J.
;
Frontera Beccaria, Antonio
URI:
http://hdl.handle.net/11201/147761
Abstract:
[eng] A combined CSD and ab initio study reveals that the interaction between the sp3 C-atom in para-substituted ArCF3 and electron rich atoms is weak (o5 kcal mol 1), somewhat directional, and thus comparable to CH-p interactions.
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