dc.contributor.author |
Dhal, Piu
|
|
dc.contributor.author |
Sasmal, Ashok
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|
dc.contributor.author |
Pilet, Guillaume
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dc.contributor.author |
Gomez, Carlos J.
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dc.contributor.author |
Bauzá Riera, Antonio
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dc.contributor.author |
Frontera Beccaria, Antonio
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dc.contributor.author |
Mitra, Samiran
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dc.date.accessioned |
2018-10-05T11:29:31Z |
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dc.identifier.uri |
http://hdl.handle.net/11201/147971 |
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dc.description.abstract |
[eng] The 1D polymer complex [Cu2(L)2(SCN)2]n (1) has been synthesised in a one-step in situ reaction of picolinaldehyde with sodium thiocyanate. The complex 1 was characterised by FTIR spectroscopy, UV/Vis spectrophotometry and elemental analysis. The crystal structure of complex 1 shows that chains of dimer complexes are formed with tetra- and pentacoordinate copper centres alternately linked by one thiocyanato and two alkoxido bridges. Variable-temperature magnetic measurements showed a strong antiferromagnetic interaction between the copper centres within the dimer mediated by the two alkoxido bridges with a J value of -374 cm-1, which is in agreement with the DFT-calculated value of -284 cm-1. EPR and cyclic voltammetric analyses were also carried out, as well as DFT calculations to evaluate the packing forces and their energies. |
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dc.format |
application/pdf |
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dc.relation.isformatof |
Versió preprint del document publicat a: https://doi.org/10.1002/ejic.201402176 |
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dc.relation.ispartof |
European Journal of Inorganic Chemistry, 2014, p. 3271-3278 |
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dc.subject.classification |
54 - Química |
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dc.subject.other |
54 - Chemistry. Crystallography. Mineralogy |
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dc.title |
Copper-assisted hemiacetal synthesis: a Cu(II) chain obtained by a one-step in situ reaction of picolinaldehyde |
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dc.type |
info:eu-repo/semantics/article |
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dc.type |
info:eu-repo/semantics/submittedVersion |
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dc.date.updated |
2018-10-05T11:29:31Z |
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dc.date.embargoEndDate |
info:eu-repo/date/embargoEnd/2075-01-01 |
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dc.embargo |
2075-01-01 |
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dc.rights.accessRights |
info:eu-repo/semantics/embargoedAccess |
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dc.identifier.doi |
https://doi.org/10.1002/ejic.201402176 |
|