Self-assembly, Binding and Dynamic Properties of Heterodimeric Porphyrin Macrocycles.

Show simple item record Ballester Balaguer, Pablo José Costa Torres, Antonio Deyà Serra, Pere Maria Frontera Beccaria, Antonio Gomila Ribas, Rosa Maria Sanders, Jeremy K. M. Oliva, Ana I. Hunter, Christopher A. 2018-10-26T10:56:13Z
dc.description.abstract [eng] A series of heterodimeric tetralactam macrocycles have been self-assembled using two kinetically labile zinc porphyrin-pyridine interactions. The stability constants have been determined by UVvis titrations in CHCl3. The stability constants depend on the degree of preorganization of the linker units connecting the interacting groups. The ability of the self-assembled macrocycles to bind a terephthalamide guest was also investigated. One of the macrocycles was used for the construction of a [2]rotaxane. The dynamic properties of this system provide insight into the exchange mechanisms that operate in complex noncovalent assemblies.
dc.format application/pdf
dc.relation.isformatof Versió postprint del document publicat a:
dc.relation.ispartof Journal of Organic Chemistry, 2005, vol. 70, num. -, p. 6616-6622
dc.rights (c) American Chemical Society , 2005
dc.subject.classification 54 - Química
dc.subject.other 54 - Chemistry. Crystallography. Mineralogy
dc.title Self-assembly, Binding and Dynamic Properties of Heterodimeric Porphyrin Macrocycles.
dc.type info:eu-repo/semantics/article
dc.type info:eu-repo/semantics/acceptedVersion 2018-10-26T10:56:14Z info:eu-repo/date/embargoEnd/2075-01-01
dc.embargo 2075-01-01
dc.rights.accessRights info:eu-repo/semantics/embargoedAccess

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