dc.contributor.author |
Casasnovas Perera, Rodrigo
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dc.contributor.author |
Frau Munar, Juan
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|
dc.contributor.author |
Ortega Castro, Joaquín
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dc.contributor.author |
Salvá Salvá, A.
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dc.contributor.author |
Donoso Pardo, Josefa Laurentina
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dc.contributor.author |
Muñoz Izquierdo, Francisco
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dc.date.accessioned |
2018-11-19T08:55:46Z |
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dc.identifier.uri |
http://hdl.handle.net/11201/148533 |
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dc.description.abstract |
[eng] Simplified versions of CBS-QB3 model chemistry were used to calculate the free energies of 36 deprotonation reactions in the gas phase. The best such version, S9, excluded coupled cluster calculation [CCSD(T)], and empirical ( Eemp) and spinorbit ( Eint) correction terms. The mean absolute deviation and root mean square thus obtained (viz. 1.24 and 1.56 kcal/mol, respectively) were very-close to those provided by the original CBS-QB3 method (1.19 and 1.52 kcal/mol, respectively). The highaccuracy of the proposed simplification and its computational expeditiousness make it an excellent choice for energy calculations on gas-phase deprotonation reactions in complex systems. |
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dc.format |
application/pdf |
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dc.relation.isformatof |
Versió preprint del document publicat a: https://doi.org/10.1002/qua.22170 |
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dc.relation.ispartof |
International Journal of Quantum Chemistry, 2010, vol. 110, p. 323-330 |
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dc.subject.classification |
54 - Química |
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dc.subject.other |
54 - Chemistry. Crystallography. Mineralogy |
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dc.title |
Simplification of the CBS-QB3 Method for Predicting Gas-Phase Deprotonation Free Energies |
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dc.type |
info:eu-repo/semantics/article |
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dc.type |
info:eu-repo/semantics/submittedVersion |
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dc.date.updated |
2018-11-19T08:55:46Z |
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dc.date.embargoEndDate |
info:eu-repo/date/embargoEnd/2075-01-01 |
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dc.embargo |
2075-01-01 |
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dc.subject.keywords |
AGE |
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dc.subject.keywords |
Chemical Kinetics |
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dc.subject.keywords |
Pyridoxamine (PM) |
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dc.subject.keywords |
DFT |
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dc.subject.keywords |
Cu (II) complexes |
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dc.rights.accessRights |
info:eu-repo/semantics/embargoedAccess |
|
dc.identifier.doi |
https://doi.org/10.1002/qua.22170 |
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