Structural characterization, recognition patterns and theoretical calculations of long-chain N-alkyl substituted purine and pyrimidine bases as ligands: on the importance of anion-pi interactions

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dc.contributor.author Fiol, J.J.
dc.contributor.author Barceló-Oliver, M.
dc.contributor.author Tasada, A.
dc.contributor.author Frontera, A.
dc.contributor.author Terrón, A.
dc.contributor.author García-Raso, A.
dc.date.accessioned 2020-05-05T06:26:10Z
dc.identifier.uri http://hdl.handle.net/11201/152223
dc.description.abstract [eng Long-chain N-alkyl substituted purine and pyrimidine bases are very interesting ligands for studying interaction motifs of biological relevance. The understanding of new types of recognition patterns between bases like RNA quartets combined with C<br>H/ , lone pair<br> and anion<br> interactions is necessary to study and control many biological processes. These interactions are essential for the packing of the crystals, and some studies have already proved their importance in biology. One of the major revelations is the importance of anion<br> interactions with both pyrimidine and purine rings. In many studies, anion<br> interactions with biologically relevant anions like chloride or bromide have been shown, anticipating that these interactions are likely present in biological systems.
dc.format application/pdf
dc.relation.isformatof Versió postprint del document publicat a: https://doi.org/10.1016/j.ccr.2012.12.013
dc.relation.ispartof Coordination Chemistry Reviews, 2013, vol. 257, num. 19-20, p. 2705-2715
dc.subject.classification 54 - Química
dc.subject.other 54 - Chemistry. Crystallography. Mineralogy
dc.title Structural characterization, recognition patterns and theoretical calculations of long-chain N-alkyl substituted purine and pyrimidine bases as ligands: on the importance of anion-pi interactions
dc.type info:eu-repo/semantics/article
dc.type info:eu-repo/semantics/acceptedVersion
dc.date.updated 2020-05-05T06:26:10Z
dc.date.embargoEndDate info:eu-repo/date/embargoEnd/2026-12-31
dc.embargo 2026-12-31
dc.subject.keywords Pi interactions
dc.subject.keywords Ab initio calculations
dc.subject.keywords Noncovalent Interactions
dc.subject.keywords X-ray structure
dc.subject.keywords purine and pyrimidine
dc.rights.accessRights info:eu-repo/semantics/embargoedAccess
dc.identifier.doi https://doi.org/10.1016/j.ccr.2012.12.013


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