Reversible Switching of the Electronic Ground State in a Pentacoordinated Copper(II) Complex

Sasmal, A.; Saha, S.; Gomez Garcia, C.J.; Desplanches, C.; Garribba, E.; Bauza, A.; Frontera, A.; Scott, R.; Butcher, R.J.; Mitra, S.

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dc.contributor.author	Sasmal, A.
dc.contributor.author	Saha, S.
dc.contributor.author	Gomez Garcia, C.J.
dc.contributor.author	Desplanches, C.
dc.contributor.author	Garribba, E.
dc.contributor.author	Bauza, A.
dc.contributor.author	Frontera, A.
dc.contributor.author	Scott, R.
dc.contributor.author	Butcher, R.J.
dc.contributor.author	Mitra, S.
dc.date.accessioned	2020-05-05T08:37:12Z
dc.identifier.uri	http://hdl.handle.net/11201/152227
dc.description.abstract	[eng] An easy reversible switching of the electronic ground state in a pentacoordinated copper(II) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(II) complex with a {dx2−y2}1 electronic configuration leads to a flip of the ground electronic configuration from {dx2−y2}1 to {dz2}1 in the metal ion.
dc.format	application/pdf
dc.relation.isformatof	Versió postprint del document publicat a: https://doi.org/10.1039/C3CC44276D
dc.relation.ispartof	Chemical Communications, 2013, vol. 49, num. 71, p. 7806-7808
dc.rights	(c) Sasmal, A. et al., 2013
dc.subject.classification	54 - Química
dc.subject.other	54 - Chemistry. Crystallography. Mineralogy
dc.title	Reversible Switching of the Electronic Ground State in a Pentacoordinated Copper(II) Complex
dc.type	info:eu-repo/semantics/article
dc.type	info:eu-repo/semantics/acceptedVersion
dc.date.updated	2020-05-05T08:37:12Z
dc.date.embargoEndDate	info:eu-repo/date/embargoEnd/2026-12-31
dc.embargo	2026-12-31
dc.rights.accessRights	info:eu-repo/semantics/embargoedAccess
dc.identifier.doi	https://doi.org/10.1039/C3CC44276D